In manganite perovskites , substitution of divalent ions ( alkaline earth metals viz . ca , sr , ba ) in the a sublattice , introduces mn4 + ions or holes into the system . it is generally considered that the concentration of holes is equal to the concentration of divalent cations because of the charge compensation by controlled valencies
2.
Ca , sr , ba ) in the a sublattice , introduces mn4 + ions or holes into the system . it is generally considered that the concentration of holes is equal to the concentration of divalent cations because of the charge compensation by controlled valencies . a number of publications exist in the literature on the synthesis of manganite perovskites